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Papillary thyroid cancer (PTC) has inflicted huge threats to the health of mankind. Metal pollution could be a potential risk factor of PTC occurrence, but existing relevant epidemiological researches are limited. The current case-control study was designed to evaluate the relationships between exposure to multiple metals and the risk of PTC. A total of 262 histologically confirmed PTC cases were recruited. Age- and gender-matched controls were enrolled at the same time. Urine samples were used as biomarkers to reflect the levels of environmental exposure to 13 metals. Conditional logistic regression models were adopted to assess the potential association. Single-metal and multi-metal models were separately conducted to evaluate the impacts of single and co-exposure to 13 metals. The increased concentration of urinary Cd, Cu, Fe, and Pb quartiles was found significant correlated with PTC risk. We also found the decreased trends of urinary Se, Zn, and Mn quartiles with the ORs for PTC. These dose-response associations between Pb and PTC were observed in the single-metal model and remained significant in the multi-metal model (OR25-50th=1.39, OR50-75th=3.32, OR>75th=7.62, p for trend <0.001). Our study suggested that PTC was positively associated with urinary levels of Cd, Cu, Fe, Pb, and inversely associated with Se, Zn, and Mn. Targeted public health policies should be made to improve the environment and the recognition of potential risk factors. These findings need additional studies to confirm in other population.
相似文献The content of fine sand (< 200 μm) in primary sludge is relatively high in Chongqing sewage treatment plant owing to the part of rainwater will be mixed with sand and discharged into the municipal pipe network. Due to the insufficient separation of the sand, different obstacles to subsequent treatment processes may increase equipment wear, reduce effective volume of the tank, or shorten the cleaning cycle. There is a common use of grit chamber for the separation. Nevertheless, the use of hydrocyclone shows an outstanding performance in cost effectiveness and ease operation. The primary sludge in a sewage plant in Chongqing was monitored, and the average concentration of total suspend solids (TSS), total sand content, and volatile suspended solid (VSS) were 40.25 g/L, 17.51 g/L, and 13.41 g/L, respectively. The size of sand in the sludge was small, and the sand below 30 μm accounted for about 70% of the total sand. It formed flocs with organic matter and was removed in subsequent process units. While the size between 30–200 μm, called fine sand, was the main separation object, accounted for about 28.5%. According to XRF and XRD analysis, the sludge composition was mainly composed of quartz (SiO2), plagioclase (Na(AlSi3O8)), and calcite (CaCO3), which were similar to the main mineral composition of surface sediments and mountain rocks in the main urban area of Chongqing. A single-factor experiment on two types (FX100 and FX50) of hydrocylones was conducted to determine their abilities concerning the separation of fine sand and enrichment of organic matters from primary sludge. FX100 and FX50 showed best performance in the case of P = 0.17 Mpa, underflow diameter (Du) = 18 mm and P = 0.20 Mpa, Du = 6 mm, respectively. The removal efficiency of fine sand by hydrocyclone FX50 was 71.39%. While, it had poor performance on organic matter enrichment and the removal efficiency of which was 17.38%. By contrast, the removal rate by FX100 reached 61.89% for fine sand and only 6.89% for organic matters detached. The superimposition effect did not appear in the serial experiments on hydrocylone FX100 and FX50, but the power is 3.5 times of that of single-stage hydrocylone FX100. Comprehensive consideration of the processing capacity per unit time and operating power, the hydrocylone FX100 was more suitable for actual operation.
相似文献Heavy metal-contaminated sediments posed a serious threat to both human beings and environment. A biosurfactant, rhamnolipid, was employed as the washing agent to remove heavy metals in river sediment. Batch experiments were conducted to test the removal capability. The effects of rhamnolipid concentration, washing time, solution pH, and liquid/solid ratio were investigated. The speciation of heavy metals before and after washing in sediment was also analyzed. Heavy metal washing was favored at high concentration, long washing time, and high pH. In addition, the efficiency of washing was closely related to the original speciation of heavy metals in sediment. Rhamnolipid mainly targeted metals in exchangeable, carbonate-bound or Fe-Mn oxide-bound fractions. Overall, rhamnolipid biosurfactant as a washing agent could effectively remove heavy metals from sediment.
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